Victor Boniface scored his first European goal of the season to give Bayer Leverkusen consecutive wins as Xabi Alonso's side beat Samuel Chukwueze's AC Milan 1-0 at the Bay Arena.
The Nigeria international thought he had given the German champions the lead before half-time, but it was ruled out by VAR.
However, he was set up by Jeremy Frimpong for the winner six minutes into the second half.
Milan's crosstown rivals Inter picked up their first win of the campaign at the San Siro thanks to a 4-0 victory over unbeaten Crvena Zvezda, Hakan Alhanoglu and the experienced Marko Arnautovic and Lautaro Martínez on goal.
Meanwhile, Robert Lewandowski scored early in both halves as Barcelona bounced back from the opening night defeat to Monaco by thrashing Young Boys 5-0.
PSV Eindhoven were the second to score their first point of the season as they drew 1–1 with Sporting Lisbon, with Dutch international midfielder Gerdy Schouten getting the opener as the visitors equalized late on.
Stade Brest had never played in the Champions League before this season.
In Tuesday's early kick-off, the French team thrashed Hamburg 4–0 for its second win in as many games, with Senegalese forward Abdoulaye Sima scoring twice.
VfB Stuttgart drew 1-1 with Sparta Prague in the other match of the evening.
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